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Functional Silicone Polymers

  • Side-Chain Mercapto-Functional Silicone Fluid
Side-Chain Mercapto-Functional Silicone Fluid

Side-Chain Mercapto-Functional Silicone Fluid

  • Product code: NV-SiF2060
  • Main components:Mercaptopropyl methylsiloxane-dimethylsiloxane copolymer
  • Cas no.:101810-99-5 or 102783-03-9
  • Product description:
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Product name:Side-Chain Mercapto-Functional Silicone Fluid

Product code: NV-SiF2060

Alias:Thiol-functional silicone fluid;Mercapto functional silicone fluid

Main components:Mercaptopropyl methylsiloxane-dimethylsiloxane copolymer;Methylmercaptopropyl Silicone Fluid

Cas no.:101810-99-5 or 102783-03-9

Molecular structure:



Characteristics:
1.Highly Reactive Thiol Groups:

The pendant mercapto (-SH) groups readily undergo efficient thiol-ene "click" reactions with unsaturated bonds (e.g., vinyl, acrylate) under UV light or in the presence of initiators.

2.Intrinsic Silicone Properties:
Possesses the inherent characteristics of polysiloxanes, including excellent thermal stability, low surface energy, and high flexibility.

3.Stable Molecular Backbone:
The dimethylsiloxane structure provides good oxidative stability and chemical inertness under a wide range of conditions.

Key Benefits :

1.Permanent modification:reacts to become a integral part of the host matrix, providing durable, non-migrating release properties, internal lubrication, and lasting surface effects.
2. Enhanced performance in radiation curing: significantly improves cure speed (reduces oxygen inhibition) and imparts greater flexibility, adhesion, and slip to UV/EB-cured films.
3. Superior & durable surface effects: delivers more stable and long-lasting release/anti-adhesion performance compared to non-reactive silicone fluids.
4. Multi-functional additive: serves as a corrosion inhibitor, anti-blocking agent, chain transfer agent, and stabilizer enhancer, adding value across formulations.

Specifications:

Appearances colorless transparent to translucent liquid

Item NV-SiF2060-10
NV-SiF2060-20

Viscosity(25℃)

5cst 10cst

Refractive index

1.4128 1.4082
Non-volatile content  (105℃,2h) 90% 90%

Applications:

1. Applications based on "thiol-ene" photoclick chemistry (core applications)
This reaction is fundamental to its use in UV/EB curing systems for building crosslinked networks or acting as a reactive diluent.
* UV/EB Curable Coatings and Inks:
Used as a reactive functional monomer in optical fiber coatings, protective coatings for electronics, 3D printing resins, etc. It significantly reduces curing shrinkage stress, enhances coating flexibility and adhesion, and improves surface lubricity.

* Optical Adhesives and Pressure-Sensitive Adhesives (PSAs):
Formulated with vinyl silicones or acrylate resins to produce high-performance adhesives with specific refractive indices, tack, and aging resistance via photocuring.

 * Polymer Network Modifier:
Incorporated as a co-monomer into networks of other vinyl polymers (e.g., acrylic resins), permanently imparting silicone-like hydrophobicity and flexibility. 

2. Applications as a high-performance release & anti-stick agent 

* Internal release agent for rubbers & plastics:
Provides lasting mold release in peroxide or sulfur-cured rubber (e.g., silicone, EPDM) and plastic processing.

* Component for release coatings: used in formulating durable release papers and films.

* Anti-stick for office equipment: prevents toner adhesion on fuser rollers in copiers/printers.

3.Other Functional Additive Applications 

* Polymer processing aid: acts as an anti-blocking agent for powders/pellets and a chain transfer agent in radical polymerizations. 

* Textile finishing: imparts durable shrink resistance to wool through chemical reaction with keratin. * Metal protection: functions as a corrosion inhibitor additive in coatings or oils and enhances coating adhesion. 

* Stability enhancer: improves the thermal-oxidative stability of dimethyl silicone fluids when blended.

Package and Storage:

25L,200L,IBC

Stored in a sealed and dark place.

Storage period : 6 months under normal temperature.


Inquiry: